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Reductive amination of carbonyl compounds in presence of glyoximate complexes of cobalt and rhodium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Bis(dimethylglyoximato)aquorhodium(III) hydride catalyzes the reductive amination of formaldehyde by aniline and of cyclohexanone by ammonia under mild conditions.

  2. 2.

    Acetic acid accelerates the reaction.

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Literature cited

  1. L. Marko and J. Bakos, J. Organomet. Chem.,81, 411 (1974).

    Google Scholar 

  2. M. Murakami, S. Suzuki, and J. W. Kang, Nippon Kagaku Zasshi,83, 1226 (1962).

    Google Scholar 

  3. M. Murakami, K. Suzuki, J. W. Kang, and M. Fujishige, Nippon Kagaku Zasshi,85, 235 (1964).

    Google Scholar 

  4. G. N. Schrauzer and R. J. Windgassen, Nature,214, 496 (1967).

    Google Scholar 

  5. G. N. Schrauzer and R. J. Windgassen, Chem. Ber.,99, 602 (1966).

    Google Scholar 

  6. B. G. Rogachev and M. L. Khidekel',Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 141.

  7. M. V. Klyuev, VINITI Dep. No. 776-78.

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Authors and Affiliations

  1. Branch of Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    M. V. Klyuev, M. V. Gapeeva & M. L. Khidekel'

Authors
  1. M. V. Klyuev
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  2. M. V. Gapeeva
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  3. M. L. Khidekel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2140–2142, September, 1978.

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Klyuev, M.V., Gapeeva, M.V. & Khidekel', M.L. Reductive amination of carbonyl compounds in presence of glyoximate complexes of cobalt and rhodium. Russ Chem Bull 27, 1889–1891 (1978). https://doi.org/10.1007/BF00929248

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  • DOI: https://doi.org/10.1007/BF00929248

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