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Pulse radiolysis study of reaction rate of O− radicals with neptunium(VI) ions in aqueous solutions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The pulse radiolysis method was used to study the reaction rate of Np(VI) with O− in aqueous alkaline solutions. The rate constants of the reaction in LiOH and NaOH solutions were determined.

  2. 2.

    The rate constant for the reduction of Np(VII) by Np(V) is independent of the LiOH concentration. The reduction proceeds more slowly in NaOH solutions.

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Literature cited

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    A. K. Pikaev & V. P. Shilov

Authors
  1. A. K. Pikaev
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  2. V. P. Shilov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2136–2139, September, 1978.

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Pikaev, A.K., Shilov, V.P. Pulse radiolysis study of reaction rate of O− radicals with neptunium(VI) ions in aqueous solutions. Russ Chem Bull 27, 1886–1889 (1978). https://doi.org/10.1007/BF00929247

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  • DOI: https://doi.org/10.1007/BF00929247

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