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Synthesis of o-substituted phosphinylbenzyl and phosphinylphenethyl alcohols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have synthesized o-phosphorus-substituted benzyl and phenethyl alcohols of formula o-R2P(O)-C6H4(CH2)nOH and o-R2P(O)CH2C6H4CH2OH (R=C6H5 or C2H5, n=1 or 2) from their methyl ethers via the corresponding bromides and acetoxy derivatives.

  2. 2.

    Hydrolysis of the substituted bromides containing a diethylphosphinyl group can be effected not only via the corresponding acetoxy derivatives but also by treatment with sodium bicarbonate.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. A. Bondarenko, E. N. Tsvetkov, E. I. Matrosov & M. I. Kabachnik

Authors
  1. N. A. Bondarenko
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  2. E. N. Tsvetkov
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  3. E. I. Matrosov
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  4. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2109–2113, September, 1978.

The authors wish to thank V. A. Svoren' for recording the PMR spectra.

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Bondarenko, N.A., Tsvetkov, E.N., Matrosov, E.I. et al. Synthesis of o-substituted phosphinylbenzyl and phosphinylphenethyl alcohols. Russ Chem Bull 27, 1862–1866 (1978). https://doi.org/10.1007/BF00929239

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  • DOI: https://doi.org/10.1007/BF00929239

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