Skip to main content
SpringerLink
Log in

Conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on Na forms of zeolites

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on the Na forms of zeolites of types A, X, Y, and L, as well as chabazite, erionite, and mordenite, in a batch microreactor has been investigated.

  2. 2.

    The conversion products of cyclohexene are cyclohexane and methylcyclopentarne. The greatest activity in this process is displayed by mordenite.

  3. 3.

    1,4-Cyclohexadiene is converted into 1,3-cyclohexadiene, cyclohexene, and benzene, the latter forming in dehydrogenation and disproportionation reactions. Zeolite NaY displays the greatest dehydrogenating activity among the zeolites investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. Kh. M. Minachev, O. K. Shchukina, M. A. Markov, and R. V. Dmitriev, Neftekhimiya,8, 37 (1968).

    Google Scholar 

  2. K. V. Topchieva, O. L. Shakhnovskaya, and E. N. Rosolovskaya, Kinet. Katal.,10, 1381 (1969).

    Google Scholar 

  3. V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, and Kh. M. Minachev, in: All-Union Conference on the Mechanism of Heterogeneous Catalytic Reactions [in Russian], Moscow (1974), Preprint 41.

  4. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1737 (1969).

  5. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and M. A. Kapustin, Izv. Akad. Nauk SSSR, Ser. Khim., 1554 (1974).

  6. R. A. Karakhanov, V. I. Garanin, V. V. Kharlamov, M. A. Kapustin, B. B. Blinov, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 445 (1975).

  7. F. A. Chernyshkova, D. V. Mushenko, and L. A. Blandina, Nef tekhimiya,14, 188 (1974).

    Google Scholar 

  8. T. Yashima, H. Suzuki, and N. Hara, J. Catal.,33, 486 (1974).

    Google Scholar 

  9. Kh. M. Minachev, D. B. Tagiev, and V. V. Kharlamov, Izv. Akad. Nauk SSSR, Ser. Khim., 1931 (1977).

  10. A. A. Kubasov, A. N. Ratov, K. V. Topchieva, and L. V. Vishnevskaya, Vestn. Mosk. Univ., Ser. Khim., No. 4, 406 (1970).

    Google Scholar 

  11. F. G. Ciapetta, R. M. Dobres, and R. W. Baker, in: Catalysis in the Petrochemical and Petroleum-Refining Industries [Russian translation], Vol. 2 (1961), p. 533.

    Google Scholar 

  12. U. M. Kurkchi, V. I. Garanin, and Kh. M. Minachev, Kinet. Katal.,9, 571 (1968).

    Google Scholar 

  13. D. W. Basset and H. W. Habgood, J. Phys. Chem.,64, 769 (1960).

    Google Scholar 

  14. V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 2406 (1975).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. V. Kharlamov, T. S. Starostina & Kh. M. Minachev

Authors
  1. V. V. Kharlamov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. S. Starostina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kh. M. Minachev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2065–2070, September, 1978.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kharlamov, V.V., Starostina, T.S. & Minachev, K.M. Conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on Na forms of zeolites. Russ Chem Bull 27, 1818–1822 (1978). https://doi.org/10.1007/BF00929229

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00929229

Keywords

Search

Navigation