Conclusions
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1.
The methods of31P-{1H}NMR spectroscopy have been used to determine the structures of hydride and nonhydride complexes of rhodium with triphenylphosphine and d-α-methylbenzyl-amine.
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2.
The interaction of the hydride phosphinoamine-containing complexes with α-acetoaminocinnamic acid leads principally to the formation of an achiral hydrideolefin complex.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2026–2030, September, 1978.
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Koroleva, L.M., Lutsenko, A.I., Latov, V.K. et al. 31P NMR spectroscopic study of the structures of mixed-hydride complexes of rhodium with triphenylphosphine and d-α-methylbenzylamine, homogeneous asymmetric hydrogenation catalysts. Russ Chem Bull 27, 1783–1786 (1978). https://doi.org/10.1007/BF00929224
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DOI: https://doi.org/10.1007/BF00929224