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A mass-spectroscopic study of compounds from the cyclopropane series 5. Electron-impact and chemical-ionization mass spectra of the geometrical isomers of alkyl- and vinyloxy-2-chlorocyclopropanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the behavior of the geometrical isomers of the alkyl-and vinyloxy-2-chlorocyclopropanes under electron impact and chemical ionization.

  2. 2.

    Chemical-ionization methods can be used to distinguish the cis and trans isomers in this series of compounds, the quasimolecular and [M+H-alkene]+ ions being the more stable in the cis forms.

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Literature cited

  1. V. I. Kadentsev, N. M. Kuznetsova, O. S. Chizhov, S. M. Shostakovskii, and T. K. Voropaeva, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2734.

  2. V. I. Kadentsev, A. Ya. Podel'ko, O. S. Chizhov, S. M. Shostakovskii, T. K. Voropaeva, and N. M. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 2015.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Kadentsev, A. Ya. Podel'ko, O. S. Chizhov, S. M. Shostakovskii, A. A. Retinskii, T. K. Voropaeva, A. B. Grigor'ev & N. S. Nikol'skii

Authors
  1. V. I. Kadentsev
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  2. A. Ya. Podel'ko
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  3. O. S. Chizhov
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  4. S. M. Shostakovskii
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  5. A. A. Retinskii
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  6. T. K. Voropaeva
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  7. A. B. Grigor'ev
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  8. N. S. Nikol'skii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2021–2025, September, 1978.

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Kadentsev, V.I., Podel'ko, A.Y., Chizhov, O.S. et al. A mass-spectroscopic study of compounds from the cyclopropane series 5. Electron-impact and chemical-ionization mass spectra of the geometrical isomers of alkyl- and vinyloxy-2-chlorocyclopropanes. Russ Chem Bull 27, 1779–1782 (1978). https://doi.org/10.1007/BF00929223

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  • DOI: https://doi.org/10.1007/BF00929223

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