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Mass-spectroscopic study of compounds from the cyclopropane series 4. Behavior of the ethers under chemical ionization

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the behavior of certain ethers under chemical ionization.

  2. 2.

    Breakdown of the quasimolecular ions of the ethers studied here gave rise to fragments characteristic of the ether and alkyl (aryl) groups and the cyclopropane ring.

  3. 3.

    The compounds in question could be separated into cis and trans isomers on the basis of a study of their CI mass spectra.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Kadentsev, A. Ya. Podel'ko, O. S. Chizhov, S. M. Shostakovskii, T. K. Voropaeva & N. M. Kuznetsova

Authors
  1. V. I. Kadentsev
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  2. A. Ya. Podel'ko
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  3. O. S. Chizhov
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  4. S. M. Shostakovskii
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  5. T. K. Voropaeva
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  6. N. M. Kuznetsova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2015–2021, September, 1978.

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Kadentsev, V.I., Podel'ko, A.Y., Chizhov, O.S. et al. Mass-spectroscopic study of compounds from the cyclopropane series 4. Behavior of the ethers under chemical ionization. Russ Chem Bull 27, 1774–1778 (1978). https://doi.org/10.1007/BF00929222

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  • DOI: https://doi.org/10.1007/BF00929222

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