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Electroreduction of polyhedrane derivatives 2. Transannular interaction of the halide atoms in 2,2,6,6-di(ethylenedioxy)-3,7-dibromobicyclo[3.3.1]nonane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Transannular interaction of the bromine atoms in 2,2,6,6-di(ethylenedioxy)-3,7-dibromobicyclo[3.3.1]nonane has been demonstrated.

  2. 2.

    The difference in the heights of the first and second electroreduction waves for 2,2,6,6-di(ethylenedioxy)-3,7-dibromocyclo[3.3.1]nonane is due to cyclization at the first-wave potential.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2001–2006, September, 1978.

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Leibzon, V.N., Mendkovich, A.S., Mairanovskii, S.G. et al. Electroreduction of polyhedrane derivatives 2. Transannular interaction of the halide atoms in 2,2,6,6-di(ethylenedioxy)-3,7-dibromobicyclo[3.3.1]nonane. Russ Chem Bull 27, 1761–1765 (1978). https://doi.org/10.1007/BF00929219

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  • DOI: https://doi.org/10.1007/BF00929219

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