Luminol oxidation with chemiluminescence 4. The theoretical mechanism of luminol activation in the presence of tetranitromethane and hydrogen peroxide

  • T. P. Vorob'eva
  • Yu. N. Kozlov
  • Yu. V. Koltypin
  • A. P. Purmal'
  • B. A. Rusin
Physical Chemistry
  • 48 Downloads

Conclusions

  1. 1.

    The oxidation of luminol by tetranitromethane follows a two-electron mechanism, aminophthaldiazine being formed as a primary oxidation product.

     
  2. 2.

    The hydrogen peroxide of luminol-hydrogen peroxide-tetranitromethane systems reacts with the tetranitromethane to form reactive intermediates which combine with the luminol to give the particles responsible for the chemiluminescence.

     

Keywords

Oxidation Hydrogen Hydrogen Peroxide Oxidation Product Luminol 

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • T. P. Vorob'eva
    • 1
  • Yu. N. Kozlov
    • 1
  • Yu. V. Koltypin
    • 1
  • A. P. Purmal'
    • 1
  • B. A. Rusin
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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