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The mechanism of benzaldehyde oxidation by ozonated oxygen

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the autooxidation of benzaldehyde. The results obtained indicate that chain initiation in this reaction follows a trimolecular mechanism with a rate constant k equal to 5.4·10−5 liter2/mole2·sec (27°C).

  2. 2.

    A study has also been made of the kinetics of the benzaldehyde oxidation by ozonated oxygen, and of the products obtained from this reaction. A mechanism has been proposed for this process, and rate constants and efficiencies of initiation measured.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    I. N. Komissarova, V. D. Komissarov & E. T. Denisov

  2. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    I. N. Komissarova, V. D. Komissarov & E. T. Denisov

Authors
  1. I. N. Komissarova
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  2. V. D. Komissarov
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  3. E. T. Denisov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1991–1996, September, 1978.

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Komissarova, I.N., Komissarov, V.D. & Denisov, E.T. The mechanism of benzaldehyde oxidation by ozonated oxygen. Russ Chem Bull 27, 1751–1756 (1978). https://doi.org/10.1007/BF00929217

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  • DOI: https://doi.org/10.1007/BF00929217

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