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Reaction of bis (β-aminoethylato) ethanolamineaquochromium chloride [(NH2CH2O)2Cr·(NH2CH2CH2OH)·H2O]C1 with aldehydes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In bis(β-aminoethylato)ethanolamineaquochromium chloride only one of the three amino groups reacts with aldehydes. The condensation is accompanied by the elimination of acetaldehyde and rupture of the C -N bond, and leads to the aldimine.

  2. 2.

    The formed coordinated aldimine exhibits a high activity in the crotonic type of condensation and is quickly converted to a polyunsaturated ligand, which then is cyclized to either the pyridine or quinoline base.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Yu. S. Dol'skaya & G. Ya. Kondrat'eva

Authors
  1. Yu. S. Dol'skaya
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  2. G. Ya. Kondrat'eva
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1207–1209, May, 1978.

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Dol'skaya, Y.S., Kondrat'eva, G.Y. Reaction of bis (β-aminoethylato) ethanolamineaquochromium chloride [(NH2CH2O)2Cr·(NH2CH2CH2OH)·H2O]C1 with aldehydes. Russ Chem Bull 27, 1050–1052 (1978). https://doi.org/10.1007/BF00929031

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  • DOI: https://doi.org/10.1007/BF00929031

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