Reaction of methylenequinones with nucleophilic agents

  • A. A. Volod'kin
  • L. I. Kudinova
  • V. V. Ershov
Brief Communications
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Conclusions

  1. 1.

    Depending on the nature of theα. substituents in methylenequinones, the predominant process is either nucleophilic addition or the one-electron transfer process.

     
  2. 2.

    α,α-Dicyano-2,6-di-tert-butylmethylenequinone forms a charge-transfer complex with amines and alcoholates.

     

Keywords

Transfer Process Nucleophilic Addition Predominant Process Nucleophilic Agent 

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Literature cited

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    D. Kh. Rasuleva, A. A. Volod'kin, V. V. Ershov, A. I. Prokof'ev, S. P. Solodovnikov, S. G. Kukes, and N. N. Bubnov, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 1446.Google Scholar
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    A. A. Volod'kin, T. I. Prokof'eva, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 1006.Google Scholar
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    G. A. Nikiforov, K. M. Dyumaev, A. A. Volod'kin, and V. V. Ershov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1962, 1836.Google Scholar
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    E. Müller, R. Mayer, U. Keilmann, and K. Scheffler, Ann. Chem.,645, 66 (1961).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • A. A. Volod'kin
    • 1
  • L. I. Kudinova
    • 1
  • V. V. Ershov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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