Catalytic conversions of tetraalkyl-and trialkylarylsilanes under the action of platinum and palladium chlorides

  • I. S. Akhrem
  • N. M. Chistovalova
  • S. M. Airapetyan
  • E. I. Mysov
  • M. E. Vol'pin
Organic Chemistry

Conclusions

  1. 1.

    Under certain conditions Pt(TV) and Pd(II) compounds catalyze the splitting of Si -C bonds in tetraalkyl-and trialkylarylsilanes.

     
  2. 2.

    In the reaction of PtCl4 with silanes in benzene in the presence of ethanol, the alkyl group split off from the Si atom adds the hydrogen of the ethanol hydroxyl group.

     
  3. 3.

    The activity of platinum complexes in reactions with silanes increases with increasing coordination unsaturation of the metal.

     
  4. 4.

    The catalytic replacement of an organic radical on the Si atom in tetraalkyl- and trialkylarylsilanes by trimethylsiloxy and ethoxy groups has been carried out.

     

Keywords

Hydrogen Chloride Hydroxyl Silane Benzene 

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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • I. S. Akhrem
    • 1
  • N. M. Chistovalova
    • 1
  • S. M. Airapetyan
    • 1
  • E. I. Mysov
    • 1
  • M. E. Vol'pin
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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