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Replacement of mercury by gold in organomercury compounds

  • A. N. Nesmeyanov
  • É. G. Perevalova
  • O. B. Afanasova
  • M. V. Tolstaya
  • K. I. Grandberg
Organic Chemistry

Conclusions

  1. 1.

    A method has been developed for the synthesis of organogold compounds of the aryl, alkenyl, cymantrenyl, and heterocyclic series from organomercury compounds.

     
  2. 2.

    Either binuclear cationic complexes of gold with the general formula [R(AuPPh3)2]BF4 or monogold organic compounds with the general formula RAuPPh3 form, depending on the nature of the radial in the organomercury compound.

     
  3. 3.

    Previously unknown organogold compounds with the general formula RAuPPh3 have been obtained from the binuclear cationic complexes of gold under the action of triphenylphosphine.

     

Keywords

Gold Mercury Organic Compound General Formula Triphenylphosphine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    A. N. Nesmeyanov, É. G. Perevalova, O. B. Afanasova, and K. I. Grandberg, Izv. Akad. Nauk SSSR, Ser. Khim., 484 (1974).Google Scholar
  2. 2.
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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • É. G. Perevalova
    • 1
  • O. B. Afanasova
    • 1
  • M. V. Tolstaya
    • 1
  • K. I. Grandberg
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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