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Codimerization and carbonylation of normal alkenes and isobutylene

  • S. D. Pirozhkov
  • K. V. Puzitskii
  • T. N. Myshenkova
  • K. G. Ryabova
Organic Chemistry
  • 31 Downloads

Conclusions

An equimolar mixture of a normal (or cyclic) alkene and an alkene with a branch at the double bond (or a tertiary alcohol) in the presence of the BF3·H2O -liquid-SO2 catalytic system under 1 atm of CO at a temperature of −30 to −40°C undergoes selective codimerization followed by carbonylation and the formation of codimeric carboxylic acids with 70 to 93% yields.

Keywords

Alcohol Carbonylation Double Bond Alkene Carboxylic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    H. Koch, Brennstoff-Chem.,36, 321 (1955).Google Scholar
  2. 2.
    H. Koch, W. Huisken, and K. E. Möller, West German Patent No. 972, 315 (1959); Ref. Zh. Khim. 23L64 (1961).Google Scholar
  3. 3.
    K. V. Pusitskii, S. D. Pirozhkov, T. N. Myshenkova, and K. G. Ryabova, Izv. Akad. Nauk SSSR, Ser. Khim., 2331 (1977).Google Scholar
  4. 4.
    S. P. McManus (editor), Organic Reactive Intermediates, Vol. 26, Academic Press, New York-London (1973), p. 216.Google Scholar
  5. 5.
    Ya. T. Éidus, S. D. Pirozhkov, and K. V. Puzitskii, Zh. Anal. Khim.,22, 1559 (1967).Google Scholar
  6. 6.
    K. V. Puzitskii, Ya. T. Éidus, and K. G. Ryabova, Izv. Akad. Nauk SSSR, Ser. Khim., 1810 (1966).Google Scholar
  7. 7.
    V. M. Potapov, Stereochemistry [in Russian], Khimiya (1976), p. 340.Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • S. D. Pirozhkov
    • 1
  • K. V. Puzitskii
    • 1
  • T. N. Myshenkova
    • 1
  • K. G. Ryabova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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