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Kinetics and mechanism of the reaction of phenylthallium dicarboxylate with tetramethyltin in methanol solution

  • I. F. Gun'kin
  • K. P. Butin
  • I. P. Beletskaya
  • O. A. Reutov
Physical Chemistry
  • 25 Downloads

Conclusions

  1. 1.

    Polarographic methods have been used to study the kinetics of the interaction of PhTlX2 type compounds (X=OCOCH3, OCOC3H7-i, OCOH, OCOCF3, OCOCH2Cl, Cl) with tetramethyltin in methanol containing tetra-n-butylammonium perchlorate.

     
  2. 2.

    Each of these reactions was overall second-order, (first-order with respect to each reactant).

     
  3. 3.

    The kinetic data and the results obtained from a study of the electrical conductance of the phenylthallium dicarboxylates suggest that each of these reactions proceeds through the intermediary of ions and ion pairs formed from the thalliumorganic compound.

     

Keywords

Methanol Electrical Conductance Perchlorate Kinetic Data Methanol Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • I. F. Gun'kin
    • 1
  • K. P. Butin
    • 1
  • I. P. Beletskaya
    • 1
  • O. A. Reutov
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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