Structural direction of the heterodiene synthesis in the reaction of oxazoles with acetylenic dienophiles

  • L. B. Medvedskaya
  • M. G. Makarov
  • G. Ya. Kondrat'eva
Biological and Physical Chemistry

Conclusions

  1. 1.

    Using the Hückel approximation for calculating the molecular orbitals, we calculated the energy levels and theπ-electron densities of some substituted oxazoles, and also the stabilization energies of the transition states when these oxazoles were reacted with acetylenic dienophiles.

     
  2. 2.

    The calculated data are in agreement with the experimental results.

     

Keywords

Energy Level Transition State Molecular Orbital Calculated Data Stabilization Energy 

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Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • L. B. Medvedskaya
    • 1
  • M. G. Makarov
    • 1
  • G. Ya. Kondrat'eva
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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