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Reaction of 1-bromo-1,2-pentadien-4-one with some nucleophiles

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    3,4-Diaminovinyl ketones are formed when 1-bromo-1,2-pentadien-4-one is reacted with secondary amines, whereas reaction with alcohols leads to the predominant formation of the esters of levulinic acid.

  2. 2.

    A new route was proposed for preparing the ketals of 1-alkoxy-2-pentyn-4-one and substituted 3-methylisoxazole derivatives.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1279–1284, June, 1973.

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Mavrov, M.V., Kucherova, V.F. Reaction of 1-bromo-1,2-pentadien-4-one with some nucleophiles. Russ Chem Bull 22, 1237–1240 (1973). https://doi.org/10.1007/BF00928595

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  • DOI: https://doi.org/10.1007/BF00928595

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