Skip to main content
Log in

Electronic spectra of some phenyl-substituted phenoxyl radicals

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Some phenoxyl radicals that are analogs of galvinoxyl and indophenoxyl were obtained and a study was made of their electronic absorption spectra. The obtained radicals do not form dimers in solutions.

  2. 2.

    Replacement of the tert-butyl groups in galvinoxyl and indophenoxyl by phenyl groups leads to a bathochromic shift in the absorption spectrum.

  3. 3.

    An increase in the pressure from 1 to 2500 atm leads to a bathochromic shift in the absorption spectra of solutions of the radicals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. V. D. Pokhodenko, Phenoxyl radicals [in Russian], Naukova Dumka, Kiev (1969).

    Google Scholar 

  2. V. A. Kuz'min, I. V. Khudjakov, P. P. Levin, A. S. Tatikolov, and N. M. Emanuel, Proceedings of the Second Conference on Degradation and Stabilization of Polymers, Arnhem (1976), p. 123.

  3. S. Claesson and L. D. Hayward, Chemica Scripta,9, 18 (1976).

    Google Scholar 

  4. P. D. Bartlett and F. Funahashi, J. Am. Chem. Soc.,84, 2596 (1962).

    Google Scholar 

  5. P. D. Bartlett and S. T. Purrington, J. Am. Chem. Soc.,88, 3303 (1966).

    Google Scholar 

  6. G. Steelink and R. E. Hansen, Tetrahedron Lett., 105 (1966).

  7. A. I. Prokof'ev, S. P. Solodovnikov, G. A. Nikiforov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 324 (1971).

  8. M. S. Kharasch and B. S. Joshi, J. Org. Chem.,22, 1435 (1957).

    Google Scholar 

  9. C. D. Cook and B. E. Norcross, J. Am. Chem. Soc.,81, 1176 (1959)).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1655–1658, July, 1977.

The authors are indebted to V. A. Kuz'min for his cooperation in the study and valuable advice.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khudyakov, I.V., Levin, P.P., De Ionge, K. et al. Electronic spectra of some phenyl-substituted phenoxyl radicals. Russ Chem Bull 26, 1525–1527 (1977). https://doi.org/10.1007/BF00928549

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00928549

Keywords

Navigation