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Pyrocatecholate and semiquinolate complexes of transition metals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new method was proposed for obtaining the o-semiquinolate complexes of the transition metals, which consists of reacting the salts of the acids of the metals, or of their halides, with substituted pyrocatechols in the presence of a base and atmospheric oxygen.

  2. 2.

    It was shown that oxidation-reduction transitions can take place between the pyrocatechol and o-semiquinolate complexes.

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Literature cited

  1. G. A. Abakumov, G. A. Razuvaev, and A. V. Lobanov, USSR Patent 527434 (1975); Byull. Izobr., No. 33, 75 (1976).

  2. F. Hein, Chemie der Komplex Verbindungen, S. Hirzel Verlag, Leipzig (1971), p. 199.

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  3. G. A. Abakumov, V. A. Muraev, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR,217, 1083 (1974).

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  4. E. Muller, K. Ley, and G. Schecte, Ber.,30, 1530 (1957).

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gorki

    G. A. Razuvaev, K. G. Shal'nova, L. G. Abakumova & G. A. Abakumov

Authors
  1. G. A. Razuvaev
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  2. K. G. Shal'nova
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  3. L. G. Abakumova
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  4. G. A. Abakumov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1642–1645, July, 1977.

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Razuvaev, G.A., Shal'nova, K.G., Abakumova, L.G. et al. Pyrocatecholate and semiquinolate complexes of transition metals. Russ Chem Bull 26, 1512–1515 (1977). https://doi.org/10.1007/BF00928544

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  • DOI: https://doi.org/10.1007/BF00928544

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