Skip to main content
SpringerLink
Log in

Thermodynamic estimate of polarity of stationary phases in gas chromatography

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method was proposed for making a thermodynamic estimate of the polarity of stationary liquid phases in gas chromatography based on the values of the differential molar free energies of solution of standard compounds.

  2. 2.

    An equation is given for calculating the energy of the dispersion and the sum of the orientation, induction, and specific interactions of the chromatographed compound with a stationary liquid phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. W. O. Mc Reynolds, J. Chromatogr. Sci.,8, 685 (1970).

    Google Scholar 

  2. P. Chovin and J. Lebbe, J. Gas. Chromatogr.,4, No. 1, 37 (1966).

    Google Scholar 

  3. R. V. Golovnya and T. A. Misharina, Izv. Akad. Nauk SSSR, Ser. Khim., No. 8 (1977).

  4. A. B. Littlewood, J. Gas. Chromatogr.,1, No. 11, 16 (1963).

    Google Scholar 

  5. Applied Science Laboratories Catalog,19, 16 (1976).

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. V. Golovnya & T. A. Misharina

Authors
  1. R. V. Golovnya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. A. Misharina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.7, pp. 1622–1625, July, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Golovnya, R.V., Misharina, T.A. Thermodynamic estimate of polarity of stationary phases in gas chromatography. Russ Chem Bull 26, 1492–1494 (1977). https://doi.org/10.1007/BF00928536

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00928536

Keywords

Search

Navigation