Conclusions
Palladium-copper alloys, which contain from 37 to 42% Cu, have both a high hydrogen permeability and a substantial catalytic activity in the de hydrogenation of 1,2-cyclohexanediol, which makes it possible to use them as membrane catalysts for this reaction.
Literature cited
V. M. Gryaznov, A. P. Mishchenko, V. P. Polyakova, N. R. Roshan, E. M. Savitskii, V. S. Smirnov, E. V. Khrapova, and V. I. Shimulis, Dokl. Akad. Nauk SSSR,211, 624 (1973).
D. L. McKinley, U. S. Patent 3439474 (1969); Ref. Zh. Khim., 12L183P (1970).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1620–1622, July, 1977.
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Mishchenko, A.P., Sarylova, M.E., Gryaznov, V.M. et al. Hydrogen permeability and catalytic activity of membranes made from palladium-copper alloys in the dehydrogenation of 1,2-cyclohexanediol. Russ Chem Bull 26, 1490–1492 (1977). https://doi.org/10.1007/BF00928535
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DOI: https://doi.org/10.1007/BF00928535