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Fluorinatedβ-sultones 46. 2-Hydrohexafluoropropane-2-sulfofluoride

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A synthesis of 2-hydrohexafluoropropane-2-sulfofluoride (II) is proposed based on the reaction of hexa(trifluoromethyl)cyclotrimethylene-1, 3, 5-trisulfone with potassium difluorids. The sulfofluoride obtained is a strong CH-acid.

  2. 2.

    By halogenating sulfofluoride n under the conditions of alkaline solvolysis, 2-chloro- and 2-bromohexafluoropropane-2-sulfofluoride are obtained.

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Literature cited

  1. G. A. Sokol'skii, V. M. Pavlov, V. M. Golovkin, and I. L. Knunyants, Khim. Geterotsikl. Soedin., 472 (1974).

  2. G. A. Sokol'skii, V. M. Pavlov, V. V. Ezhov, and I. L. Knunyants, Khim. Geterotsikl. Soedin., 45 (1974).

  3. A. F. Eleev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 397 (1974).

  4. N. P. Aktaev, G. F. Il'in, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim, 1112 (1977).

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  6. N. P. Aktaev, O. G. Eremin, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1117 (1977).

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Authors and Affiliations

  1. Institute for Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. F. Eleev, G. A. Sokol'skii & I. L. Knunyants

Authors
  1. A. F. Eleev
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  2. G. A. Sokol'skii
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  3. I. L. Knunyants
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1573–1577, July, 1977.

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Eleev, A.F., Sokol'skii, G.A. & Knunyants, I.L. Fluorinatedβ-sultones 46. 2-Hydrohexafluoropropane-2-sulfofluoride. Russ Chem Bull 26, 1444–1448 (1977). https://doi.org/10.1007/BF00928525

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  • DOI: https://doi.org/10.1007/BF00928525

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