Conclusions
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1.
The optical absorption of e −tr in propanol arises from a 1s → vc transition that is itself determined by the effective short-range final state potential. The value of μ0, the microscopic mobility, is greater than μe¯s, and corresponds to a quasi-free state.
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2.
Formation of e −tr in glassy polar organic matrices is possible only if the electronic energy is much greater than kT, the energy required for forming the polarized trap.
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3.
The estimated value of the microscopic electron mobility can be applied to liquid polar systems, since passage from liquid to glass does not markedly alter its value.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1503–1506, July, 1977.
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Kostin, A.K., Vannikov, A.V. Photocurrents in the pulsed-laser photolysis of trapped electrons in propyl alcoholγ-irradiated at 77°K. Russ Chem Bull 26, 1380–1383 (1977). https://doi.org/10.1007/BF00928509
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DOI: https://doi.org/10.1007/BF00928509