Conclusions
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1.
The mechanism of the catalytic reaction between hydroperoxide and phosphite consists in equilibrium complex formation between the catalyst and the phosphite and the hydroperoxide, and the reaction of the phosphite with coordinated molecules of the hydroperoxide.
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2.
For the catalysis, there is required the formation of reaction-capable complexes between the catalyst and the hydroperoxide in the first coordination sphere of the metal ion, whose lifetime at 19° is 10−4 sec.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1271–1276, June, 1976.
The authors are indebted to O. P. Yablonskii for valuable information and for his evaluation of the work.
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Pobedimskii, D.G., Nasybullin, S.A., Chebotareva, E.G. et al. Mechanism of the catalytic reaction between hydroperoxides and phosphates. Russ Chem Bull 25, 1228–1232 (1976). https://doi.org/10.1007/BF00928057
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DOI: https://doi.org/10.1007/BF00928057