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Hydrogenation of 2-methyl-2-butene on Na forms of zeolites

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the activity of the Na forms of zeolites of type A, X, Y, chabazite, erionite, L, and mordenite in the hydrogenation of 2-methyl-2-butene; depending on the SiO2/Al2O3 ratio in the zeolite, the activity of the catalysts passes through a maximum at 180, 200, and 220‡.

  2. 2.

    The apparent activation energy increases when going from faujasltes to mordenite.

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Literature cited

  1. V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, Kh. M. Minachev, and A. A. Goryachev, Izv. Akad. Nauk SSSR, Ser. Khim. (1975), No. 4.

  2. Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and é. é. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1737 (1969).

  3. S. S. Khvoshchev, S. P. Zhdanov, and M. A. Shubaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 1004 (1972).

  4. Kh. M. Minachev, V. I. Garanin, and V. B. Kharlamov, Izv. Akad. Nauk SSSR, Ser. Khim., 835 (1970).

  5. J. Jermen, Catalytic Transformations of Hydrocarbons [Russian translation], Mir (1972), p. 78.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 673–676, March, 1975.

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Kharlamov, V.V., Garanin, V.I., Tagiev, D.B. et al. Hydrogenation of 2-methyl-2-butene on Na forms of zeolites. Russ Chem Bull 24, 597–599 (1975). https://doi.org/10.1007/BF00927488

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  • DOI: https://doi.org/10.1007/BF00927488

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