Autodissociation of anhydrous perchloric acid

  • A. I. Karelin
  • Z. I. Grigorovich
  • V. Ya. Rosolovskii
Brief Communications


  1. 1.

    Pure anhydrous perchloric acid melts without decomposition to perchloric anhydride and the monohydrate.

  2. 2.

    The dissociation rate of perchloric acid to give perchloric anhydride increases rapidly at temperatures above −30‡.



Anhydride Perchloric Acid Monohydrate Dissociation Rate Anhydrous Perchloric Acid 
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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • A. I. Karelin
    • 1
  • Z. I. Grigorovich
    • 1
  • V. Ya. Rosolovskii
    • 1
  1. 1.Institute of New Chemical ProblemsAcademy of Sciences of the USSRChernogolovka

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