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Some reactions of 1-epoxyisopropyl-o-carborane

  • L. I. Zakharkin
  • G. G. Zhigareva
  • V. D. Kenzhetaeva
Organic and Biological Chemistry

Conclusions

  1. 1.

    When 1-epoxyisopropyl-o-carborane is treated with hydrogen halide acids or with alcohols in the presence of boron trifluoride the oxide ring is opened on the side of the primary carbon atom of the epoxy group.

     
  2. 2.

    When 1-epoxyisopropyl-o-carborane is treated with weakly basic nucleophilic reagents the oxide ring is also opened on the side of the primary carbon atom of the epoxy group. Treatment with strongly basic nucleophilic reagents leads to cleavage of the epoxy group and the formation of o-carborane.

     

Keywords

Oxide Hydrogen Alcohol Boron Epoxy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    M. Fein, J. Bohinski, N. Mayes, N. Schwartz, and M. Cohen, Inorg. Chem.,2, 1111 (1963).Google Scholar
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    R. Grimes, Carboranes [Russian translation], Mir (1974).Google Scholar
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    J. Green, N. Mayes, A. Kofloby, and M. Fein, J. Polymer Sci., PartB2, 109 (1964).Google Scholar
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    N. Mayes and J. Green, Inorg. Chem.,4, 1082 (1965).Google Scholar
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    A. I. L'vov and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2653 (1967).Google Scholar
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    K. A. Krasuskii and G. T. Pimogin, Ukr. Khim. Zh.,5, 349 (1930).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • G. G. Zhigareva
    • 1
  • V. D. Kenzhetaeva
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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