Vibrational spectra of crystalline nickelecene and cobalticene

  • V. Bom
  • B. Hechter
  • M. Shushani
  • I. A. Koningstein
  • E. M. Smirnova
  • Ya. M. Kimel'fel'd
  • E. V. Bykova
  • V. T. Aleksanyan
Physical Chemistry

Conclusions

  1. 1.

    The IR spectra of crystalline nickelecene and cobalticene, as well as the Raman spectrum of nickelecene, were obtained at low temperatures, and an interpretation of them was given.

     
  2. 2.

    The fine structure of the IR bands of nickelecene at low temperatures agrees with the x-ray diffraction data, obtained for the crystal at R~20‡.

     
  3. 3.

    In the Raman spectrum of nickelecene in comparison with other metallocenes, a reverse order of arrangement of the frequencies of the metal-ring vibrationsΝ4 andΝ16 is observed.

     

Keywords

Raman Spectrum Fine Structure Diffraction Data Vibrational Spectrum Reverse Order 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • V. Bom
    • 1
    • 2
    • 3
  • B. Hechter
    • 1
    • 2
    • 3
  • M. Shushani
    • 1
    • 2
    • 3
  • I. A. Koningstein
    • 1
    • 2
    • 3
  • E. M. Smirnova
    • 1
    • 2
    • 3
  • Ya. M. Kimel'fel'd
    • 1
    • 2
    • 3
  • E. V. Bykova
    • 1
    • 2
    • 3
  • V. T. Aleksanyan
    • 1
    • 2
    • 3
  1. 1.Institute of SpectroscopyAcademy of Sciences of the USSRMoscow
  2. 2.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow
  3. 3.Carlton UniversityOttawaCanada

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