Conclusions
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1.
The reaction of ethyldichlorosilane with organic solvents is expressed more weakly than in the case of methyldichlorosilane, which is due to the steric effect of the C2H5 group.
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2.
Ethyldichlorosilane when dissolved in nitrobenzene exists as the trans conformer.
Literature cited
M. G. Vornokov and G. I. Lebedeva, Third International Symposium on Organosilicon Chemistry, Madison, 1972, Abstract of Paper, p. 57.
M. G. Voronkov and G. I. Lebedeva, Izv. Akad. Nauk SSSR, Ser. Khim., 1973, 2473.
M. E. Rudakov and Yu. A. Pentin, Optika i Spektroskopiya,21, 426 (1966).
Yu. A. Pentin and S. E. Rudakova, Vestn. Mosk. Univ., Ser. Khim.,1966, 3.
O. M. Dzhafarov, K. A. Karasharle, and I. A. Kostryukov, Zh. Fiz. Khim.,45, 1244 (1971).
M. G. Voronkov and A. Ya. Deich, Dokl. Akad. Nauk SSSR,163, 337 (1966).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2597–2600, November, 1973.
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Lebedeva, G.I., Voronkov, M.G. Spectroscopic study of reaction of ethyldichlorosilane with organic solvents. Russ Chem Bull 22, 2531–2533 (1973). https://doi.org/10.1007/BF00926412
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DOI: https://doi.org/10.1007/BF00926412