Infrared spectra of monofluoropolynitroalkylnitramines
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The vibration frequency of the C-F bond in the IR spectra of the monofluoropolynitroalkylnrtramines was identified. The frequency as a function of the electronegativity of the second substituent attached to the nitramine group was explained as being due to the shielding effect of the nitramine group.
An intramolecular hydrogen bond between the nitramine and hydroxyl groups is present in N-(2-fluoro-2,2-dinitroethyl)-N-nitroamino alcohols.
KeywordsHydrogen Alcohol Hydroxyl Hydrogen Bond Infrared Spectrum
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