Conclusions
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1.
The vibration frequency of the C-F bond in the IR spectra of the monofluoropolynitroalkylnrtramines was identified. The frequency as a function of the electronegativity of the second substituent attached to the nitramine group was explained as being due to the shielding effect of the nitramine group.
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2.
An intramolecular hydrogen bond between the nitramine and hydroxyl groups is present in N-(2-fluoro-2,2-dinitroethyl)-N-nitroamino alcohols.
Literature cited
L. T. Eremenko, N. G. Zhitomirskaya, and G. V. Oreshko, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 2674.
L. T. Eremenko and N. G. Zhitomirskaya, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 2805.
L. T. Eremenko, N. G. Zhitomirskaya, and G. V. Oreshko, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 2680.
L. T. Eremko, D. A. Nesterenko, and N. S. Natsibullina, Izv. Akad. Nauk SSSR, Ser. Khim.,1970, 1335.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2593–2595, November, 1973.
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Zhitomirskaya, N.G., Nesterenko, D.A. & Eremenko, L.T. Infrared spectra of monofluoropolynitroalkylnitramines. Russ Chem Bull 22, 2525–2527 (1973). https://doi.org/10.1007/BF00926410
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DOI: https://doi.org/10.1007/BF00926410