Conclusions
A linear relationship between the charges on the phosphorus and oxygen atoms of the phosphoryl group, calculated on the basis of the orbital electronegativities, and the sum of the induction constants of the substituents at the phosphorus atom was found for compounds of the R3PO type.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2491–2494, November, 1973.
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Raevskii, O.A., Bel'skii, V.E. & Zverev, V.V. Estimation of the effective charges in phosphoryl compounds on the basis of the orbital electronegativity. Russ Chem Bull 22, 2432–2434 (1973). https://doi.org/10.1007/BF00926387
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DOI: https://doi.org/10.1007/BF00926387