Skip to main content
Log in

Migration of a cation between oxygen atoms in the ion pair of the anion radical of 3,3',5,5'-tetra-tert-butyldiphenoquinone

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Depending on the cation and solvent, the frequency of migration of a cation between oxygen atoms in the anion radical of 3,3', 5, 5'-tetra-tert-butyldiphenoquinone varies, increasing with increasing solvating ability of the solvent.

  2. 2.

    Together with “intramolecular” migration of the cation, exchange is detected between the ion pairs, in which the cation is differently solvated by the solvent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. M. P. Khakhar, B. S. Prabhananda, and M. R. Das, J. Amer. Chem. Soc.,89, 3100 (1967).

    Google Scholar 

  2. T. A. Claxton, J. Oakes, and M. C. R. Symons, Trans. Faraday Soc.,64, 596 (1968).

    Google Scholar 

  3. J. Oakes and M. C. R. Symons, Trans. Faraday Soc.,66, 10 (1970).

    Google Scholar 

  4. J. Oakes, J. Stater and M. C. S. Symons, Trans. Faraday Soc.,66, 546 (1970).

    Google Scholar 

  5. T. E. Gough and P. R. Hindle, Trans. Faraday Soc.,66, 2420 (1970).

    Google Scholar 

  6. T. E. Gough and, P. R. Hindle, Canad. J. Chem.,47, l698, 3393 (1969);49, 1529, 2412 (1971).

    Google Scholar 

  7. J. Oakes, M. C. R. Symons, and T. A. Claxton, J. Amer. Chem. Soc.,93, 3769 (1971).

    Google Scholar 

  8. J. C. Chippendale and E. Warhurst, Trans. Faraday Soc.,64, 2332 (1968).

    Google Scholar 

  9. P. S. Gill and T. E. Gough, Trans. Faraday Soc.,64, 1997 (1968).

    Google Scholar 

  10. J. H. Freed and G. K. Fraenkel, J. Chem. Phys.,39, 326 (1963).

    Google Scholar 

  11. G. K. Fraenkel, J. Phys. Chem.,71, 139 (1967).

    Google Scholar 

  12. A. Kerrington and E. MacLachlan, Magnetic Resonance and Its Use in Chemistry [Russian transla tion], “Mir” (1970).

  13. P. J. Zandstra and S. I. Weissman, J. Amer. Chem. Soc.,84, 4408 (1962).

    Google Scholar 

  14. M. Schwarz, Uspekhi Khimii,39, 1260 (1970).

    Google Scholar 

  15. M. Schwarz, Anionic Polymerization [Russian translation], “Mir” (1970).

  16. N. Hirota, J. Phys. Chem.,71, 131 (1967).

    Google Scholar 

  17. A. I. Prokof'ev, S. P. Solodovnikov, A. A. Volodkin, and V. V. Ershov, Dokl. Akad. Nauk SSSR,204, 114 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2459–2463, November, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prokof'ev, A.I., Solodovnikov, S.P., Volod'kin, A.A. et al. Migration of a cation between oxygen atoms in the ion pair of the anion radical of 3,3',5,5'-tetra-tert-butyldiphenoquinone. Russ Chem Bull 22, 2403–2406 (1973). https://doi.org/10.1007/BF00926381

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00926381

Keywords

Navigation