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Investigation of dialkyldithiocarbamates of copper (II), nickel (II), and zinc by the method of anodic polarography

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the anodic oxidation of copper, nickel, and zinc N, N-dialkyldithiocarbamates in acetonitrile on a rotating platinum electrode, polarograms of two waves were obtained. The waves in the potential interval (+ 0.35 to +1.00 V) correspond to oxidation of the initial compounds, while the waves in the interval (+1.12 to +1.52 V) correspond to oxidation of the oxidation products formed in the first process.

  2. 2.

    The second wave in the spectrum of N,N-dialkyldithiocarbamates is not associated with oxidation of the corresponding thiuram disulfides.

  3. 3.

    The nature of the ligand has a substantial influence on the values of the potentials of the anodic waves of copper N, N-dialkyldithiocarbamates.

  4. 4.

    A dependence of the potentials of the anodic waves on the nature of the central metal ion in copper, nickel, and zinc, N, N-dialkyldithiocarbamates was established.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    A. N. Zverev & V. G. Vinogradova

Authors
  1. A. N. Zverev
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  2. V. G. Vinogradova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2440–2444, November, 1973.

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Zverev, A.N., Vinogradova, V.G. Investigation of dialkyldithiocarbamates of copper (II), nickel (II), and zinc by the method of anodic polarography. Russ Chem Bull 22, 2385–2388 (1973). https://doi.org/10.1007/BF00926377

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  • DOI: https://doi.org/10.1007/BF00926377

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