Conclusions
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1.
The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs with a tricoordinated phosphorus atom were determined.
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2.
A graphical method was proposed for the analysis of the data of the method of dipole moments of cyclic compounds.
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3.
In all the compounds studied, a chair conformation with axial (or diaxial for the spiro compound) arrangement of the alkoxy group with a gauche-orientation of the methoxyl and ethoxyl radicals and a cisorientation of the phenoxy group is realized.
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For Communication 3, see [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2426–2431, November, 1973.
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Arbuzov, B.A., Arshinova, R.P., Vul'fson, S.G. et al. Steric structure of phosphorus-containing heterocycles. Russ Chem Bull 22, 2372–2376 (1973). https://doi.org/10.1007/BF00926374
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DOI: https://doi.org/10.1007/BF00926374