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Integral intensity of C-H stretching vibration band in IR spectra of o-carboranes as a function of the substituent site and nature

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The integral intensity of the C-H stretching vibration band was measured in the spectra of more than 50 substituted o-carboranes.

  2. 2.

    The induction mechanism was confirmed for the transmission of the effect of the substituent X in the system\(\begin{array}{*{20}c} X & H \\ \backslash & / \\ C & { - C} \\ \backslash & / \\ {B_{10} } & {H_{10} } \\ \end{array} \) on the C-H bond. The mechanism for the transmission of the effect is more complicated in the case where the substituent is attached to the B atom in the 3 position of the carborane ring.

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Literature cited

  1. L. A. Leites, L. E. Vinogradova, V. N. Kalinin, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1016 (1968).

  2. L. E. Vinogradova, L. A. Leites, V. N. Kalinin, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2848 (1969).

  3. L. A. Leites, L. E. Vinogradova, V. N. Kalinin, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2596 (1970).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. E. Vinogradova, L. A. Leites, V. V. Gedymin, V. N. Kalinin & L. I. Zakharkin

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  1. L. E. Vinogradova
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  2. L. A. Leites
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  3. V. V. Gedymin
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  4. V. N. Kalinin
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  5. L. I. Zakharkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2817–2820, December, 1973.

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Vinogradova, L.E., Leites, L.A., Gedymin, V.V. et al. Integral intensity of C-H stretching vibration band in IR spectra of o-carboranes as a function of the substituent site and nature. Russ Chem Bull 22, 2755–2757 (1973). https://doi.org/10.1007/BF00926161

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  • DOI: https://doi.org/10.1007/BF00926161

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