Synthesis and study of some properties of triphenylsilicon, triphenylgermanium, triphenyltin and triphenyllead derivatives of manganese and rhenium π-cyclopentadienyltricarbonyls

  • A. N. Nesmeyanov
  • K. N. Anisimov
  • N. E. Kolobova
  • Yu. V. Makarov
Brief Communications
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Conclusions

  1. 1.

    The triphenylsilicon, triphenylgermanium, triphenyltin and triphenyllead derivatives of π-cyclopentadienyltricarbonylmanganese and π-cyclopentadienyltricarbonylrhenium were synthesized. The heterolysis of the CCp-E bond in these compounds was studied.

     
  2. 2.

    A compound was obtained that contained two different types of manganese carbonyl groupings in the molecule: (CO)3MnC5H4Sn(C6H5) [Mn(CO)5]2.

     

Keywords

Manganese Carbonyl Carbonyl Grouping Rhenium Triphenyltin 

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Literature cited

  1. 1.
    A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and Yu. V. Makarov, Dokl. Akad. Nauk SSSR,178, 1335 (1968).Google Scholar
  2. 2.
    A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and B. I. Baryshnikov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 193 (1963).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • K. N. Anisimov
    • 1
  • N. E. Kolobova
    • 1
  • Yu. V. Makarov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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