Synthesis and study of some properties of triphenylsilicon, triphenylgermanium, triphenyltin and triphenyllead derivatives of manganese and rhenium π-cyclopentadienyltricarbonyls
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The triphenylsilicon, triphenylgermanium, triphenyltin and triphenyllead derivatives of π-cyclopentadienyltricarbonylmanganese and π-cyclopentadienyltricarbonylrhenium were synthesized. The heterolysis of the CCp-E bond in these compounds was studied.
A compound was obtained that contained two different types of manganese carbonyl groupings in the molecule: (CO)3MnC5H4Sn(C6H5) [Mn(CO)5]2.
KeywordsManganese Carbonyl Carbonyl Grouping Rhenium Triphenyltin
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