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MBr-AlBr3-solv systems at 25°

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The isotherms of MBr-AlBr3-Et2O (M=Na, K, Rb) at 25° are characterized by the crystallization branches of MBr and the AlBr3·Et2O etherate. The successive crystallization of AlBr3·Et2O, CsAlBr4 and CsBr was established in the CsBr-AlBr3-Et2O system at 25°.

  2. 2.

    The isotherm of KBr-AlBr3-C7H8 at 25° has the crystallization branches of Al2Br6·C7H8, KAl2Br7, KAlBr4, and KBr. A stratification region and the crystallization fields of Al2Br4·C7H8, Rb(Cs)Al2Br7 and Rb(Cs)Br were established for the Rb(Cs)Br-AlBr3-C7H8 systems.

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    V. I. Mikheeva, S. M. Arkhipov & A. E. Pruntsev

Authors
  1. V. I. Mikheeva
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  2. S. M. Arkhipov
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  3. A. E. Pruntsev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2810–2811, December, 1973.

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Mikheeva, V.I., Arkhipov, S.M. & Pruntsev, A.E. MBr-AlBr3-solv systems at 25°. Russ Chem Bull 22, 2746–2747 (1973). https://doi.org/10.1007/BF00926158

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  • DOI: https://doi.org/10.1007/BF00926158

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