Conclusions
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1.
A method was developed for determining the limiting adsorption and its temperature dependence by dilatometric measurements of the adsorption system: zeolite-liquid adsorbtive.
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2.
The limiting adsorption and its temperature coefficient were measured for the system: n-pentane-zeolite NaX in the range 30–150°. The temperature coefficient, calculated by the Nikolaev-Dubinin method, shows satisfactory agreement with the experimentally measured value.
Literature cited
B. P. Bering and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 122 (1969).
M. M. Dubinin and V. A. Astakhov, Izv. Akad. Nauk SSSR, Ser. Khim., 5 (1971).
B. P. Bering, A. G. Zhukovskaya, B. Kh. Rakhmukov, and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 30 (1968).
K. M. Nikolaev and M. M. Dubinin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1165 (1958).
V. V. Zhukov and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 958 (1972).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2798–2801, December, 1973.
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Bering, E.P., Rakhmukov, B.K. & Serpinskii, V.V. Experimental determination of limiting adsorption and its temperature dependence. Russ Chem Bull 22, 2734–2736 (1973). https://doi.org/10.1007/BF00926153
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DOI: https://doi.org/10.1007/BF00926153