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Synthesis of σ-ferrocenyl and σ-ferrocenoyl derivatives of iron and tungsten cyclopentadienylcarbonyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new method was proposed for the synthesis of cyclopentadienylirondicarbonyl-σ-ferrocenyl.

  2. 2.

    The ferrocenoyl complexes of iron and tungsten were synthesized.

  3. 3.

    The decarbonylation of the ferrocenoyl complex of tungsten by heating gave cyclopentadienyltungstentricarbonyl-σ-ferrocenyl in quantitative yield. The decarbonylation of the iron complex goes under more drastic conditions, with partial decomposition.

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Literature cited

  1. A. N. Nesmeyanov, L. G. Makarova, and V. N. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 892 (1971).

  2. A. N. Nesmeyanov, L. G. Makarova, and V. N. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim. 1600 (1972).

  3. G. G. Dvoryantseva, S. L. Portnova, K. I. Grandberg, S. P. Gubin, and Yu. N. Sheinker, Dokl. Akad. Nauk SSSR,160, 1075 (1965).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, L. G. Makarova & V. N. Vinogradova

Authors
  1. A. N. Nesmeyanov
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  2. L. G. Makarova
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  3. V. N. Vinogradova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2796–2798, December, 1973.

The authors express their gratitude to P. V. Petrovskii for discussing the NMR spectra.

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Nesmeyanov, A.N., Makarova, L.G. & Vinogradova, V.N. Synthesis of σ-ferrocenyl and σ-ferrocenoyl derivatives of iron and tungsten cyclopentadienylcarbonyls. Russ Chem Bull 22, 2731–2733 (1973). https://doi.org/10.1007/BF00926152

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  • DOI: https://doi.org/10.1007/BF00926152

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