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Reaction of N,N-dichloroarylsulfonamides with 1,1,3-trichloropropene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We accomplished both the heterolytic and the homolytic addition of N,N-dichloroarylsulfonamides to 1,1,3-trichloropropene.

  2. 2.

    1-(p-Chlorobenzenesulfonyl)-2-trichloromethylaziridine and 1-(benzenesulfonyl)-2-trichloromethylaziridine were obtained in high yield by the dehydrochlorination of 1,1,1,3-tetrachloro-2-(N-pchlorobenzenesulfonamido)propane and 1,1,1,3-tetrachloro-2-(N-benzenesulfonamido)propane.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2793–2796, December, 1973.

The authors express their gratitude to V. I. Dostovalova for taking the NMR spectra and their interpretation.

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Rybakova, N.A., Pochkailo, N.A. & Kiseleva, L.N. Reaction of N,N-dichloroarylsulfonamides with 1,1,3-trichloropropene. Russ Chem Bull 22, 2728–2730 (1973). https://doi.org/10.1007/BF00926151

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  • DOI: https://doi.org/10.1007/BF00926151

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