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Charge-transfer band in spectrum of aluminum bromide complex with benzophenone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Employing UV spectroscopy and cryoscopy, it was shown that benzophenone forms two different complexes with aluminum bromide: (C6H5)2CO·AlBr3 and (C6H5)2CO·2AlBr3.

  2. 2.

    A charge-transfer band, with a maximum at 440 nm, was detected in the UV spectrum of the complex: (C6H5)2CO·2AlBr3.

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Literature cited

  1. G. Briegleb, Elektronen-Donator-Acceptor-Komplexe, Berlin (1961).

  2. E. N. Gur'yanova, I. P. Gol'dshtein, and I. P. Romm, in: The Donor-Acceptor Bond [in Russian], Chapters II and III, Khimiya (1973).

  3. R. S. Becker, J. Mol. Spectry.,3, 1 (1959).

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  4. I. P. Romm, E. N. Gur'yanova, E. N. Kharlamova, R. R. Shifrina, N. N. Shapet'ko, and K. A. Kocheshkov, Dokl. Akad. Nauk SSSR,189, 810 (1969); I. P. Romm, E. N. Kharlamova, and E. N. Gur'yanova, Zh. Obshch. Khim.,42, 2246 (1972).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    I. P. Romm, L, I. Belen'kii & E. N. Gur'yanova

  2. L. Ya. Karpov Physicochemical Institute, USSR

    I. P. Romm, L, I. Belen'kii & E. N. Gur'yanova

Authors
  1. I. P. Romm
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  2. L, I. Belen'kii
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  3. E. N. Gur'yanova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2783–2784, December, 1973.

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Romm, I.P., Belen'kii, L.I. & Gur'yanova, E.N. Charge-transfer band in spectrum of aluminum bromide complex with benzophenone. Russ Chem Bull 22, 2717–2718 (1973). https://doi.org/10.1007/BF00926146

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  • DOI: https://doi.org/10.1007/BF00926146

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