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Ability of As=S group to form the hydrogen bond

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The As=S group is capable of forming a hydrogen bond with phenol by functioning as the proton acceptor, in which connection the proton-acceptor capacity depends on the environment of the arsenic atom. The stability of the formed hydrogen bonds is somewhat higher than for the P=S group, but it is considerably lower than for the As=O group.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2778–2779, December, 1973.

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Shagidullin, R.R., Izosimova, S.V. & Lamanova, I.A. Ability of As=S group to form the hydrogen bond. Russ Chem Bull 22, 2711–2712 (1973). https://doi.org/10.1007/BF00926144

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  • DOI: https://doi.org/10.1007/BF00926144

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