Conclusions
The reactions of tris(trimethylsilylmethyl)stannyllithium with tert-butyl peroxide, trimethyl(tertbutylperoxy)silane, triphenyl(tert-butylperoxy)germane, benzoyl peroxide and dicyclohexyl peroxydicarbonate proceed with a heterolytic cleavage of the peroxide group. In the unsymmetrical peroxides the less shielded oxygen atom is subjected to attack.
Literature cited
G. A. Razuvaev, V. A. Shushunov, V. A. Dodonov, and T. G. Brilkina, in: Organic Peroxides, D. Swern (editor), John Wiley and Sons, Inc., New York (1972), p. 141.
H. Gilman and C. H. Adams, J. Am. Chem. Soc.,47, 2816 (1925).
S. O. Lawson and N. C. Jang, J. Am. Chem. Soc.,81, 4230 (1959).
G. A. Baramkt, H. S. Chang, and J. T. Edvard, Can J. Chem.,40, 441 (1962).
D. D. Devis and C. E. Gray, Organometal. Chem. Rev.,A6, 283 (1970).
N. S. Vyazankin, G. A. Razuvaev, E. N. Gladyshev, and T. G. Gurikova, Dokl. Akad. Nauk SSSR,155, 1108 (1964).
N. S. Vyazankin, G. A. Razuvaev, O. A. Kruglaya, and G. S. Semchikova, J. Organometal. Chem.,6, 474 (1966).
O. A. Kruglaya, G. S. Kalinina, B. I. Petrov, and N. S. Vyazankin, J. Organometal. Chem.,46, 51 (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2776–2778, December, 1973.
Rights and permissions
About this article
Cite this article
Basalgina, T.A., Kruglaya, O.A., Kalinina, G.S. et al. Reactions of tris(trimethylsilylmethyl)-stannyllithium with peroxides. Russ Chem Bull 22, 2708–2710 (1973). https://doi.org/10.1007/BF00926143
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00926143