Conclusions
The1H chemical shifts of sulfur-containing 1-organylsilatranes of type YCH2Si(OCH2-CH2)3N, where Y ′ RS, RS(O), and of sulfonium salts of the silatrane series of type [YCH2Si-(OCH2CH2)3N]I−, where Y = RR′S+, are determined by the valence state of the sulfur atom and the steric stresses. The molecular conformation of the studied compounds was established.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 464–467, February, 1979.
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Voronkov, M.G., Tandura, S.N., Sorokin, M.S. et al. PMR spectra of sulfur-containing 1-organylsilatranes. Russ Chem Bull 28, 431–433 (1979). https://doi.org/10.1007/BF00925907
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DOI: https://doi.org/10.1007/BF00925907