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Redox potentials of ferrocene-ferricenium cation system in H2O-CH3COOH-H2SO4

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The effect of the H2SO4 concentration and ratio of the components in a mixed aqueous-organic solvent on the real potential values of the Fec/Fec+ system was studied.

  2. 2.

    A mathematical equation was derived that expresses the value of the real potential (Ep) as a function of the H2SO4 concentration and amount of organic solvent in an aqueous-organic medium.

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Literature cited

  1. B. P. Nikol'skii, V. I. Pal'chevskii, A. A. Pendin, and Kh. M. Yakubov, in: Redoxometry [in Russian], Khimiya, Leningrad (1975), p. 255.

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Author information

Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Balusov, Yu. D. Koreshkov, V. T. Solomatin, S. P. Gubin & V. A. Drozdov

  2. Branch of Chemistry and Chemical Technology of the Institute of Inorganic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, Krasnoyarsk

    V. A. Balusov, Yu. D. Koreshkov, V. T. Solomatin, S. P. Gubin & V. A. Drozdov

  3. I. P. Bardin Scientific-Research Institute of Ferrous Metallurgy, Moscow

    V. A. Balusov, Yu. D. Koreshkov, V. T. Solomatin, S. P. Gubin & V. A. Drozdov

Authors
  1. V. A. Balusov
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  2. Yu. D. Koreshkov
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  3. V. T. Solomatin
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  4. S. P. Gubin
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  5. V. A. Drozdov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 457–459, February, 1979.

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Balusov, V.A., Koreshkov, Y.D., Solomatin, V.T. et al. Redox potentials of ferrocene-ferricenium cation system in H2O-CH3COOH-H2SO4 . Russ Chem Bull 28, 424–426 (1979). https://doi.org/10.1007/BF00925903

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  • DOI: https://doi.org/10.1007/BF00925903

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