Conclusions
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1.
A system of equations, describing the process of separating a reacting two-component mixture in a chromatographic column, was solved. The exit curves are plotted.
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2.
Curves, describing the change in the amount of complex in the mixture on exit from the column as a function of the logarithm of the decomposition rate constant of the complex, were constructed on the basis of the calculations for a set of kinetic parameters of the reaction.
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3.
It was shown that it is theoretically possible to determine the rate constants of complex-formation reactions from the results of two chromatographic experiments.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 448–450, February, 1979.
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Melenevskii, A.T., El'kin, G.É. & Samsonov, G.V. Chromatographic determination of rate constants of a reversible reaction involving two components. Russ Chem Bull 28, 415–417 (1979). https://doi.org/10.1007/BF00925899
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DOI: https://doi.org/10.1007/BF00925899