Conclusions
Tri(dimethylamino)phosphine and trimethyl phosphite react with the p-dimethylaminoanil of acetoacetic ester to give 1∶1 bipolar adducts with a P-N bond.
Literature cited
N. A. Polezhaeva, M. N. Agafonov, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim.,1979, No. 3.
B. A. Arbuzov, N. A. Polezhaeva, and M. N. Agafonov, Izv. Akad. Nauk SSSR, Ser. Khim.,1979, 436.
F. Sachs and W. Wolff, Chem. Ber.,36, 3221 (1903).
F. Ramirez, A. V. Patwardhan, and C. P. Smith, J. Am. Chem. Soc.,87, 4973 (1965).
F. Ramirez, A. V. Patwardhan, H. J. Kugler, and C. P. Smith, J. Am. Chem. Soc.,89, 6276 (1967).
B. A. Arbuzov, N. A. Polezhaeva, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 2281.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 445–447, February, 1979.
The authors express their gratitude to E. I. Gol'dfarb and R. G. Gainullina for taking the31P and1H NMR spectra.
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Arbuzov, B.A., Polezhaeva, N.A. Structure of reaction products of acetoacetic ester p-dimethylaminoanil with trimethyl phosphite and Tri(dimethylamino)phosphine. Russ Chem Bull 28, 413–414 (1979). https://doi.org/10.1007/BF00925898
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DOI: https://doi.org/10.1007/BF00925898