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Synthesis of o-substituted phosphinyl-, phosphinylmethyl-and phosphinylethylphenols

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    o-Diethyl- and o-diphenylphosphinylphenol and o-(2-diethylphosphinylethyl)phenol are prepared by dealkylating the corresponding o-phosphorus-substituted anisoles with hydrobromic acid.

  2. 2.

    o-Diethyl- and o-diphenylphosphinylmethylphenol are prepared by Arbuzov rearrangement of the corresponding salicyl phosphinite esters.

  3. 3.

    o-(2-Diphenylphosphinylethyl)phenol is prepared by cleavage of coumaran with sodium diphenylphosphide followed by oxidation of the resulting phosphinophenol.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. A. Bondarenko, E. N. Tsvetkov, E. I. Matrosov & M. I. Kabachnik

Authors
  1. N. A. Bondarenko
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  2. E. N. Tsvetkov
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  3. E. I. Matrosov
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  4. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 432–435, February, 1979.

The authors wish to thank V. A. Svoren' for recording the PMR spectra.

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Bondarenko, N.A., Tsvetkov, E.N., Matrosov, E.I. et al. Synthesis of o-substituted phosphinyl-, phosphinylmethyl-and phosphinylethylphenols. Russ Chem Bull 28, 399–403 (1979). https://doi.org/10.1007/BF00925894

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  • DOI: https://doi.org/10.1007/BF00925894

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