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Phenyl-substituted 1,4-benzoquinone diazides. 3. Thermal decomposition of 2,6-diphenyl-1, 4-benzoquinone diazide in carbon tetrachloride

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reduced shielding of the carbonyl group in the cyclohexadienone carbene allows this group to participate, as well as the carbene reaction center, in reactions of the carbene.

  2. 2.

    The isomerization of o-quinolide compounds into the p isomers, involving intramolecular migration of a trichloromethyl group, has been observed.

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Literature cited

  1. V. V. Ershov and G. A. Nikiforov, Usp. Khim.,44, 1775 (1975).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    L. G. Plekhanova, K. de Jong, G. A. Nikiforov & V. V. Ershov

  2. AKZO Research Laboratories, Arnhem, Netherlands

    L. G. Plekhanova, K. de Jong, G. A. Nikiforov & V. V. Ershov

Authors
  1. L. G. Plekhanova
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  2. K. de Jong
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  3. G. A. Nikiforov
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  4. V. V. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSR, Seriya Khimicheskaya, No. 2, pp. 409–411, February, 1979.

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Plekhanova, L.G., de Jong, K., Nikiforov, G.A. et al. Phenyl-substituted 1,4-benzoquinone diazides. 3. Thermal decomposition of 2,6-diphenyl-1, 4-benzoquinone diazide in carbon tetrachloride. Russ Chem Bull 28, 378–379 (1979). https://doi.org/10.1007/BF00925889

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  • DOI: https://doi.org/10.1007/BF00925889

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